Abstract
From 2005 to 2013, volatile organic compounds (VOCs) and other trace gases were continuously measured at a suburban site in Hong Kong. The measurement data showed that the concentrations of most air pollutants decreased during these years. However, ozone (O3) and total non-methane hydrocarbon levels increased with the rate of 0.23 ± 0.03 and 0.34 ± 0.02 ppbv/year, respectively, pointing to the increasing severity of photochemical pollution in Hong Kong. The Hong Kong government has ongoing programs to improve air quality in Hong Kong, including a solvent program implemented during 2007–2011, and a diesel commercial vehicle (DCV) program since 2007. From before to after the solvent program, the sum of toluene, ethylbenzene and xylene isomers decreased continuously with an average rate of −99.1 ± 6.9 pptv/year, whereas the sum of ethene and propene increased by 48.2 ± 2.0 pptv/year from before to during the DCV program. Despite this, source apportionment results showed that VOCs emitted from diesel exhaust decreased at a rate of −304.5 ± 17.7 pptv/year, while solvent related VOCs decreased at a rate of −204.7 ± 39.7 pptv/year. The gasoline and liquefied petroleum gas vehicle emissions elevated by 1086 ± 34 pptv/year, and were responsible for the increases of ethene and propene. Overall, the simulated O3 rate of increase was lowered from 0.39 ± 0.03 to 0.16 ± 0.05 ppbv/year by the solvent and DCV programs, because O3 produced by solvent usage and diesel exhaust related VOCs decreased (p < 0.05) by 0.16 ± 0.01 and 0.05 ± 0.01 ppbv/year between 2005 and 2013, respectively. However, enhanced VOC emissions from gasoline and LPG vehicles accounted for most of the O3 increment (0.09 ± 0.01 out of 0.16 ± 0.05 ppbv/year) in these years. To maintain a zero O3 increment in 2020 relative to 2010, the lowest reduction ratio of VOCs/NOx was ∼1.5 under the NOx reduction of 20–30% which was based on the emission reduction plan for Pearl River Delta region in 2020.
Highlights
As a special administrative region of China, Hong Kong has been one of the most developed regions in Asia since the early 1990s
The results suggest that the air quality in Hong Kong was generally in good shape
The increasing trend of the total non-methane hydrocarbons (NMHCs) was opposite to that indicated by the emission inventory in Hong Kong, in which the volatile organic compounds (VOCs) emissions decreased from 49,790 tons in 2005 to 30,620 tons in 2013 (HKEPD, 2013)
Summary
As a special administrative region of China, Hong Kong has been one of the most developed regions in Asia since the early 1990s. The DCV program is considered to be essentially continuous from 2007 to the present Another important measure on VOC control in Hong Kong was the solvent program, which focused on regulating the maximum contents of VOCs in solvent products, i.e., printing ink, hairspray, architectural paint, air fresheners, paint and coatings used in vehicle refinishing, adhesives and sealants. It required the installation of emission reduction devices on printing machines.
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