Evaluation of the atmospheric chloride deposition in the Danube hydrological zone of Bulgaria

Abstract

Estimation of the long-term groundwater recharge based on the chloride mass balance method is easy for practical applications. This method is reliable only if the atmospheric chloride deposition is known. The direct measuring of this deposition is difficult and time consuming. In this study, the chloride deposition at the catchment scale is assessed based on the export of chloride with river waters (including baseflow), as the net groundwater recharge in the studied catchments is usually low, and its contribution to the exports of salts is insignificant. For the purpose of this study, a 25-year-long time series of discharge and chloride content (from 1951 to 1975) is processed, as the quality of river waters for this period is considered natural and unaffected by human activity in the studied catchments. The obtained value of the atmospheric chloride deposition for North Bulgaria is in the range of 2.5–2.8 g/m2/a based on representative stations. This is the first estimate of the atmospheric chloride deposition in the country, which may be used for assessment of the long-term groundwater recharge in North Bulgaria.