Abstract

Tannery wastewater is composed of a complex mixture of organic and inorganic components from various processes that can critically pollute the environment, especially water bodies if discharged without treatment. In this study, integrated vesicular basalt rock and local plant species were used to establish a horizontal subsurface flow constructed wetland system and to investigate the treatment efficiency of tannery wastewater. Four pilot units were vegetated with P. purpureum, T. domingensis, C. latifolius, and E. pyramidalis, and a fifth unit was left unvegetated (control). The constructed wetland units in horizontal subsurface flow systems were effective in removing total chromium (Cr), chemical oxygen demand (COD), and 5-day biological oxygen demand (BOD5) from the inflow tannery wastewater. The removal efficiency reached up to 99.38, 84.03, and 80.32% for total Cr, COD, and BOD5, respectively, in 6 days of hydraulic retention time (HRT). The removal efficiency of total suspended solid (TSS), total phosphorus (TP), and nitrate (NO3−) of the constructed wetland units reached a maximum of 70.59, 62.32, and 71.23%, respectively. This integrated system was effective for treating tannery wastewater, which is below the Ethiopian surface water standard discharge limit set to BOD5 (200 mg L−1), COD (500 mg L−1), total Cr (2 mg L−1), NO3− (20 mg L−1), TSS (50 mg L−1), and TP (10 mg L−1).

Highlights

  • Tanning industries use several types of chemicals at different unit processes starting from preservation to the finished leather products

  • The diluted wastewater from this pond was collected in a high-density polyethylene (HDPE) plastic tank with a volume of 2,000 L to feed the CWUs

  • The constructed wetland units worked with an average hydraulic loading rate (HLR) of 0.0357 m d−1 (3.57 cm d−1)

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Summary

Introduction

Tanning industries use several types of chemicals at different unit processes starting from preservation to the finished leather products. The tannery wastewater is characterized by complex mixtures of organic and inorganic chemicals with high concentrations of Cr, BOD, COD, TDS, strong color, and pH (Buljan et al, 2011). The various chemicals in the tannery effluents pollute water bodies, soil, and air, and seriously affect human health and other biological organisms (Sivaram and Barik, 2019). Cr is one of the chemical components in the tannery wastewater which can be oxidized from +III to +VI oxidation states. Cr (VI) is more toxic than Cr (III). It can cause carcinogenic (IARC, 1990; Rowbotham et al, 2000), mutagenic (McCarroll et al, 2010), and teratogenic (Elsaieed and Nada, 2002) effects on humans and other animals

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