Abstract

The merits of different modulated molecular beam detection systems are discussed and the application of modern data handling methods described. It is shown that by using time domain analysis together with fourier transform techniques, information on the kinetics of surface processes is obtained. Data at a number of excitation frequencies is obtained in a single experiment. A means of detecting non-linear surface processes, and an accurate method for the determination of reaction orders is given. The origin of spurious coherent signals is considered, and finally the application of the techniques is illustrated with data obtained from an investigation of the interaction of modulated As4 beams with GaAs surfaces.

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