Evaluation of state-to-state transitions and squeezing properties in molecules of the type H– X using the recently derived analytical IBT

Abstract

We employ the methodological iterative Bogoliubov transformations (IBT) [Int. J. Quantum Chem. 94 (2003) 179], in which analytical expressions for the transition probabilities between quantum states of an anharmonic system interacting with a low intensity time dependent field were derived, for the evaluation of state-to-state transitions in diatomic molecules of the type H– X. We extend the former result in the calculation of the squeezing and dispersive properties of the system, and evaluate it for the same kind of molecules.