Abstract

Thermal barrier coatings (TBCs) were made on cylindrical substrates with radii of 5, 10 and 15 mm. In addition to the cylindrical substrates, the TBC were also made on a plate substrate. First, NiCoCrAlY was pressureless plasma sprayed as a bond coating, and then zirconia with 8 mol% yittria was air plasma sprayed as the top coating. The TBC specimens were exposed in an atmosphere of air at 1373 K for 0, 200 and 500 h. The radial strain was measured with the strain scanning method using hard synchrotron X-rays. The hoop and axial stresses of the cylindrical specimens were measured using laboratory X-rays with successive removal of the surface by polishing. Using these measured stresses and strains, the distributions of the 3-dimensional components of the residual stress in the top coating were determined. The spalling stress became a maximum at about 50 μm from the interface. This position corresponded to the location of initiation of the spalling cracks. The value of the measured maximum spalling stress ...

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