Abstract

Near-infrared (NIR) chemical imaging is an emerging technique with the potential for the detection of contaminants in the environmental field. In this study the potential of NIR chemical imaging (NIR-CI) to predict concentrations of nutrients (total nitrogen, total phosphorus) and indicator microorganisms (Escherichia coli) in surface water was investigated. Chemical images of multiple samples were obtained simultaneously using a pushbroom imaging system operating in the 950–1650 nm wavelength range with spectral resolution of 7 nm. Using partial least squares regression models, the relationship between these pollutants and NIR spectral data extracted from the chemical images in samples of aqueous surface water and filtered residue from surface water was assessed. When calibration models were tested on an independent data set, it was found that models developed on filtered residue spectra outperformed those developed on aqueous samples. For samples of filtered residue, the performance of the calibrations achieved for total nitrogen was reasonable (R2 > 0.75); however, performance for total phosphorus and E. coli was poor (R2 < 0.5). Lower concentrations of these parameters were detected in the surface water samples included in the study (<1 mg L−1 and <20 colony-forming units per 100 mL, respectively), a likely reason for the poor performance. The results indicate that NIR-CI has the potential for screening samples in which the contaminant concentration exceeds 1 mg L−1.

Full Text
Paper version not known

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.