Abstract

The National Air Quality Forecast Capability (NAQFC) and an experimental version of the NAQFC (NAQFC-β) provided flight decision support during the July 2011 NASA DISCOVER-AQ field campaign around Baltimore, Maryland. Ozone forecasts from the NAQFC and NAQFC-β were compared to surface observations at six air quality monitoring stations in the DISCOVER-AQ domain. A bootstrap algorithm was used to test for significant bias and error in the forecasts from each model. Both models produce significant positively biased forecasts in the morning while generally becoming insignificantly biased in the afternoon during peak ozone hours. The NAQFC-β produces higher forecast bias, higher forecast error, and lower correlations than the NAQFC. Forecasts from the two models were also compared to each other to determine the spatial and temporal extent of significant differences in forecasted ozone using a bootstrap algorithm. The NAQFC-β tends to produce an average background ozone mixing ratio of at least 3.51 ppbv greater than the NAQFC throughout the domain at 95 % significance. The difference between the two models is significant during the overnight and early morning hours likely due to the way the Carbon Bond 5 mechanism in the NAQFC-β handles reactive nitrogen recycling and organic peroxide species. The value of information each model provides was tested using a static cost-loss ratio model. By standard measures of forecast skill, the NAQFC generally outperforms the NAQFC-β; however, the NAQFC-β provides greater value of information. This is because standard measures of forecast skill often hide the sensitivity of end users’ needs to forecast error.

Highlights

  • The NASA Earth Venture Program on Deriving Information on Surface conditions from COlumn and VERtically resolved observations relevant to Air Quality (DISCOVER-AQ) used a combination of aircraft and ground stations to assess the air quality around Baltimore, Maryland, in July 2011

  • The updated chemical mechanism in the National Air Quality Forecast Capability (NAQFC)-β tends to produce higher surface ozone mixing ratios than the mechanism used in the NAQFC (Saylor and Stein 2012)

  • Statistical tests were performed to evaluate the skill of these two numerical models in predicting surface ozone, to determine the statistical significance of any differences in surface ozone predicted by the two models, and to assess the change in the value of information as a result of the updated mechanism

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Summary

Introduction

The NASA Earth Venture Program on Deriving Information on Surface conditions from COlumn and VERtically resolved observations relevant to Air Quality (DISCOVER-AQ) used a combination of aircraft and ground stations to assess the air quality around Baltimore, Maryland, in July 2011. The NAQFC-β was provided by the NOAA Air Resources Laboratory to help address a secondary objective of the DISCOVER-AQ campaign, which was to evaluate state-of-the-art air quality models. The combination of these air quality models and the unique flight-decision support needed during DISCOVER-AQ yielded an ideal test-bed for addressing the value of information in real-time decision scenarios. CMAQ model version 4.6 is based on the Carbon Bond 2005 (CB05) gas-phase chemical mechanism (Yarwood et al 2005) with modal size-distributed aerosol components (Foley et al 2010) Both the NAQFC and NAQFC-β are run with the same meteorological fields, emissions inventories, and horizontal grid spacing of 12 km

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