Abstract

Lactic acid (LA) is an organic acid produced by fermentation or chemical synthesis. It plays a crucial role in the pharmaceutical, food and plastic industries. In the fermentation of, for example, grass silage, LA and different compounds are produced. To purify lactic acid, researchers have tried to investigate membrane technology to achieve a high yield of lactic acid permeance. This study tested four commercially available nanofiltration membranes (NF270, MPF-36, Toray NF, and Alfa Laval NF). Nanofiltration experiments were performed to investigate the rejection levels of lactic acid from a binary solution by using distinct molecular weight cut off membranes. All of the experiments were conducted with a lab-scale cross-flow membrane unit. Different operating conditions (pH, temperature) were studied for each membrane; the optimal process condition was found at 25 °C and pH 2.8. With higher temperatures and pH, an increase in LA rejection was observed. The MPF-36 membrane shows the lowest lactic acid rejection yield of 7%, while NF270 has the highest rejection yield of 71% at 25 °C and pH 2.8. These results will be helpful in the future to understand both the interaction of lactic acid permeance through nanofiltration membranes and process scale-up.

Highlights

  • Lactic acid (LA) is an essential chemical compound used as a flavour, acidifier, and preservative in the food industry

  • Nanofiltration is used to study the transport of binary solutions

  • The experiment showed that nanofiltration is useful for lactic acid separation but depends strongly on the characteristics of the membrane regarding the selective layer charge, the pore size, and the composition

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Summary

Introduction

Lactic acid (LA) is an essential chemical compound used as a flavour, acidifier, and preservative in the food industry. The pharmaceutical, cosmetic and polymers industries use lactic acid as a raw material to develop commercial products [1]. Lactic acid is produced in two ways: fermentation (biotechnological process) and chemical synthesis. Different feedstocks have been utilised for lactic acid production to replace the oil-based material. Green biomass, like grass or seaweed, can be fermented to obtain lactic acid [2]. LAB, such as Lactobacillus delbrueckii [3] or Bacillus coagulants strains A20, A369, A107, and A59 [4], can convert sugars like fructose, glucose, arabinose, etc., into lactic acid, ethanol, butyric, propionic, acetic, and caproic acid, and other organic acids [5]. Fermentation has many advantages, the production of other chemical compounds besides lactic acid is not desirable in the industries mentioned above, since they require a pure form of this compound (LA) [6]. LA without impurities or in a highly refined form is mandatory for industrial application [7]

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