Abstract

Hydrothermal, dilute acid, and steam explosion pretreatment methods, were evaluated for their efficiency to improve the methane production yield of three Mediterranean agricultural lignocellulosic residues such as olive tree pruning, grapevine pruning, and almond shells. Hydrothermal and dilute acid pretreatments provided low to moderate increase in the digestibility of the biomass samples, whereas steam explosion enabled the highest methane yields to be achieved for almond shells at 232.2 ± 13.0 mL CH4/gVS and olive pruning at 315.4 ± 0.0 mL CH4/gVS. Introduction of an enzymatic prehydrolysis step moderately improved methane yields for hydrothermal and dilute acid pretreated samples but not for the steam exploded ones.

Highlights

  • The replacement of conventional fossil fuels with alternative sources is dictated by a number of concerns, regarding future sustainability of feedstock, energy security, reduction of greenhouse gas emissions, and support of local economy

  • During this work we evaluated three different agricultural residues, namely, vine and olive pruning and almond shells, as a potential feedstock for the production of biogas via anaerobic digestion

  • The chosen agricultural species could be of high economic interest in countries in the Mediterranean basin, due to the high amount of lignocellulosic residues that are currently underutilized and whose potential to be converted into high-value biofuels has hardly been explored

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Summary

Introduction

The replacement of conventional fossil fuels with alternative sources is dictated by a number of concerns, regarding future sustainability of feedstock, energy security, reduction of greenhouse gas emissions, and support of local economy. To meet these significant challenges extensive research for different feedstocks and energy production processes is currently underway. To this end, solid, liquid, and gaseous biofuels that are produced from renewable sources and waste streams of biological origin are very promising. The high volumetric methane content of the biogas promises an high energy yield

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