Abstract
Five derivatives of thioisocoumarin bearing aromatic and nonaromatic ring systems have been synthesized and characterized to unravel the importance of interactions due to the presence of a sulfur atom in generating packing motifs in the crystalline state. Apart from the well characterized interactions like C–H⋯S, a CS⋯π interaction is found in one of the case studies. The importance of such interactions in crystal structure packing along with routine C–H⋯π and π⋯π interactions is examined in the context of overall stability in the molecular assembly. The CS⋯π interactions in comparison to CO⋯π interactions have been analyzed using the Cambridge Structural Database (CSD).
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.