Abstract

Interconnect development for planar solid oxide fuel cells is considered a vital technical area requiring focused research to meet the performance and cost goals. A commercial ferritic stainless steel composition for oxidation resistance properties was investigated by measuring the weight gain due to air exposure at fuel cell operating temperature. A surface treatment process was found to produce a dense, adherent scale and to reduce the oxide scale growth rate significantly. A process was also identified for coating the surface of the alloy to reduce the in-plane resistance and potentially to inhibit chromium oxide evaporation. The combination of treatments provided a very low resistance through the scale. The resistance measured was as low as 10 mΩ-cm2 air. The resistance value was stable over several thermal cycles. The treated samples were exposed to a variety of atmospheres that were relevant in fuel cell operation to evaluate changes in scale morphology. Analysis of the scale after such exposure showed the presence of a stable composition. When exposed to a dual atmosphere (air and hydrogen on opposite sides of the metal sheet), however, the scale composition contained a mixture of phases. Additional process modifications are planned to reduce the effect of dual-atmosphere exposure.

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