Abstract
Excess free energy of mixing ΔFtotal ΔFAB in the binary mixtures of long chain alchols and amines in nonpolor solvent carbon tetrachloride have been calculated with the help of our proposed equation. The novelty of our equation is that it involves separate estimation of excess free energy of mixing due to interaction between polar-polar molecules, polar-induced nonpolar molecules and induced nonpolar molecules and a picture of molecular interaction in these mixtures has been elicited with the help of these parameters.
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