Abstract

The application of phase change materials (PCMs) has been verified as an effective strategy for improving energy efficiency and reducing greenhouse gas emissions. Biocomposite PCMs (Bc-PCM) exhibit large latent heat, chemical stability, and a wide temperature range. In this study, thermal conductivity improved Bc-PCM (TBc-PCM) was made via vacuum impregnation with graphene nanoplatelets (GNPs). Chemical stability analysis and thermal performance analyses of the Bc-PCM and TBc-PCM were carried out as well as building energy simulations and thermal comfort analyses. Our results show Bc-PCM showed a higher heat storage capacity and enthalpy value compared to TBc-PCM. TBc-PCM exhibited a 378% increase in thermal conductivity compared to Bc-PCM. Building energy simulation results revealed that annual heating and cooling energy consumption decreased as the thickness of the PCM layer increased. In addition, the Bc-PCM with a larger PCM capacity was more effective in reducing energy consumption during the heating period. On the other hand, the cooling energy reduction effect was greater when TBc-PCM with high thermal conductivity was applied because of the high heat transfer during the cooling period. Thermal comfort evaluation revealed it was more comfortable when PCM was applied.

Highlights

  • The building sector contributes 30% of total primary energy consumption [1,2,3]

  • Bc-phase change materials (PCMs) and thermal conductivity improved Biocomposite PCMs (Bc-PCM) (TBc-PCM) were placed in a sheet of plastic material, which had a thickness of 10, 20 and 30 mm, and was applied between the insulation and the gypsum plaster board

  • We confirmed that the Fourier transform infrared spectroscopy (FTIR) absorption spectra of Bc-PCM and TBc-PCM are almost same, with absorption peaks of from 2935 to 2846, 1739, 1701, 1389, 1083, and 717 cm−1, caused by stretching vibration of functional groups of C−O, −CH2, and −CH3

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Summary

Introduction

The building sector contributes 30% of total primary energy consumption [1,2,3]. effective and sustainable ways to enhance thermal comfort conditions and energy efficiency in buildings are required [4,5]. Latent heat storage materials have a high storage density at small temperature intervals [9,10] In this respect, the application of phase change materials (PCMs) in building envelope components has been verified as an effective strategy for building energy efficiency improvement [11] and greenhouse gas emission reduction [5,12]. Organic PCMs are mainly used in latent heat storage systems because they have good compatibility with other materials, no super-cooling, and high heat of fusion, and can be used over a wide temperature range [16,17]. Bc-PCMs are highly appreciated given the fact that they are non-toxic, renewable, non-expensive and accessible [18,19] These Bc-PCMs are encased in a sheet of plastic material and used to stabilize room temperature when installed behind drywall on walls or ceilings. Wen et al [22]

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