Abstract

Environmental pollution is a worldwide concern, especially when caused by sewage dumping into water bodies. Many substances are present in industrial or domestic wastewater, causing contamination in superficial water collection. Surfactants stand out for being widely used both industrially and domestically. The use of detergents and many types of surfactants was increased during the Covid-19 pandemic period, a fact observed in the levels in the effluent sample analysis from a Sewage Treatment Plant (STP) - Vila City around 21 and 39 mg L-1 in this period. This work evaluated the surfactant concentrations in the primary and secondary treatment units of the Vila City STP, in the city of Paranavaí-PR.-Brazil. In addition, the use of a post-treatment by slow sand filtration and adsorption by activated carbon produced from spent coffee grounds in the complementary removal of surfactants was proposed. A mixed bed with sand and activated carbon columns was made on a pilot scale, and filtration/adsorption runs were performed simulating slow filtration with rates of approximately 15 m3 m-2 day-1. The parameters used for the efficiency removal evaluation in a pilot plant run were: turbidity (NTU) and surfactant concentrations. The removal of surfactant concentrations was about 9% and 7% in the Upflow Anaerobic Sludge Bed reactors (UASB-RALF) and in the secondary treatment, respectively, at the STP – Vila City units. In the post-treatment proposed by filtration/adsorption, bed columns on a pilot scale plant obtained a reduction of approximately 94% in terms of turbidity (NTU) and 95% in terms of surfactant removal.
 Keywords: activated carbono, coffee poder, effluent, surfactants.

Highlights

  • Environmental pollution is a worldwide concern, mainly caused by the discharge of sewage into water bodies

  • Considering the need to control the levels of surfactants and having spent coffee dreg as a by-product and adsorbent potential, the present study aims to verify the efficiency of surfactant removal at the Vila City Sewage Treatment Plant (STP) in the city of Paranavaí - Paraná - Brazil

  • The results showed that in the conventional process used by the sewage treatment plant the removal of surfactants in the effluent was around 9% after UASB-reator anaeróbio de leito fluidizado (RALF) and 7% after secondary treatment

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Summary

Introduction

Environmental pollution is a worldwide concern, mainly caused by the discharge of sewage into water bodies. To measure the level of pollution and contamination, environmental legislation uses some quality indicators in samples collected, such as oils and greases, surfactants, organic matter, or phosphorus (Metcalf and Eddy, 2014). Among these parameters, surfactants stand out for being widely used in industries, and daily in households as a detergent; in this way, surfactants are among the main pollutants found in sewers (Gül, 2020). Considering the presence of surfactants in industrial and domestic sewers, which often exceed the limit concentrations for dumping in river waters, it is necessary to implement techniques and processes to reduce the concentration of these compounds, such as, for example, filtration and adsorption

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