Abstract

This paper describes the evaluation of several data-processing options for a flow-based sample processor with a well-stirred mixing chamber. Data-processing options evaluated include peak-height, peak-area and time-interval methods with different choices of reference points. Results are compared with theoretical expectations and effects of experimenal parameters on the different methods are compared by using relative error coefficients. It is found that theoretical equations based on a kinetic model for the system describe shapes of calibration equations very well and predict slopes of calibration plots to within a few percent of experimental values. These results show that other less rigorous treatments can lead to conclusions that are valid only for selected sets of circumstances.

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