Evaluating the impact threshold of soluble salts on preservation of earthen site in Emperor Qin Shi Huang’s mausoleum

Abstract

The recurrent crystallization and subsequent volumetric expansion of soluble salts pose significant risks to earthen sites, particularly those with archaeological remains on their surfaces. Therefore, timing interventions based on salt content is crucial. This study focuses on the effects of soluble salt content on the earthen site within the burial pits of the Qin Mausoleum, with a particular emphasis on defining safe salinity levels. A mixture of Na2SO4/NaCl salts in a 1:1 mass ratio was added to remodelled soil cakes, which were then aged in a climate chamber for several months. The area of salt expansion on the soil cakes’ surfaces was measured using a deep-focus microscope to assess damage. The results indicate a sudden increase in salt expansion when salinity exceeded 0.1%. Additionally, re-evaluations of these soil cakes years later allowed for the exploration of mechanisms and the feasibility of assessing soil surface expansion and friability at different stages of the earthen site’s lifecycle, including excavation and display. These findings provide preliminary scientific bases and novel methodologies for the further preventive conservation of heritage earthen sites.