Abstract
Melting experiments have established three important eutectics in this system: (1) the Si3N4‐Mg2SiO4 binary eutectic composition, 0.07Si3N4+0.93Mg2SiO4 at 1560°C, (2) the Si2N2O‐Mg2SiO4 binary eutectic composition, 0.17Si2N2O+ 0.83Mg2SiO4 at 1525°C, and (3) the Si3N4‐Si2N2O‐Mg2SiO4 ternary eutectic composition, 0.04Si3N4+0.14Si2N2O+0.82Mg2SiO4 at 1515°C. Systematic replacement of MgO with CaO in the ternary eutectic reduced its melting temperature to 1325°C for a CaO/MgO molar ratio of 0.67. The results of this study are discussed in relation to fabrication, microstructure, and high‐temperature strengths.
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Schedule a callMore From: Journal of the American Ceramic Society. American Ceramic Society
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