Abstract
Acid–base interaction of holmium(III) and lutecium(III) complexes with octaphenyltetraazaporphyrin in AcOH and AcOH–benzene and AcOH–H2SO4 systems was found to involve one nitrogen meso-atom. Stability constants of the obtained acid forms are determined. Solvoprotolytic dissociation of complexes in the systems based on AcOH is studied and its mechanism is discussed.
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