Abstract

In this work, we report the influence of silver nanoparticles of different size on the optical behavior of the europium-doped hydroxyapatite nanorods. The presence of ionic, plasmonically visible and silent (ultra-small) silver nanoparticles on the surface of europium-doped apatite and its influence on its luminescent behavior were discussed. It was found that ionic silver exhibited a concentration-dependent enhancement in emission at the excitation of europium. For plasmonically visible and silent silver nanoparticles, the emission observed was due to the contribution of the ligand passivating the europium-doped hydroxyapatite nanoparticle surface. These nanoparticles due to its luminescent and biocompatible nature can be used for bioimaging applications.

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