Abstract
AbstractFaint yellow transparent single crystals of Eu4OCl6 (1) and Eu4OBr6 (2) grow from fluxes that emerge from reaction mixtures containing EuX3 (X Cl, br), Eu2O3 and lithium metal in 6:1:8 molar ratios at elevated temperatures in tantalum ampoules. Both crystallize with the Ba4OCl6 type structure (hexagonal, P63mc, Z = 2, 1: a = 944.07(4), c = 715.60(4) pm and 2: a = 982.04(4), c = 749.69(5) pm) with „isolated”︁ O2− centered Eu4 tetrahedra.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Zeitschrift für anorganische und allgemeine Chemie
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
