Abstract
Resume Rotational Raman spectra of O2 has been recorded at room temperature and 1 to 15 atmospheres with a spectral resolution of 0.2 cm-1. At low densities, the intensities and positions of the satellites of the Rayleigh and S(N) lines (N = 1,3,5,7) has been measured and found in good agreement with calculations of Altmann et al. except for the Rayleigh line. The pressure broadening of the spectral profile of the S(1) triplet has been investigated. We show that, even at 15 atm. where the three lines strongly overlap, this triplet can be fitted by three lorentzian curves, the self broadening coefficient of which is found equal to 5.5 × 10-2 cm-1/amagat.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
