Abstract

The formation of solid solutions of lithium and nickel oxides, containing more than 2 at Li %, requires the presence of oxygen under a pressure which must exceed 10 −3 torr at 933 K. Solid solutions containing a maximum of 2 at Li % however can be prepared under a reduced pressure of oxygen (< 10 −4 Torr). Mechanisms are proposed to explain, in both cases, the incorporation of lithium ions in the nickel-oxide lattice.

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