Abstract
The reactions between potassium tetrachloroplatinate(II) and 2,-propenol, 2-butenol, 3-buten-2-ol have been investigated. First the complex [PtCl 3(olefin)] − is formed, followed by a rearrangement of this into a cis-[PtCl 2(diolefin)] complex. The mechanism of the reaction and the structure of the complexes formed have been studied by NMR.
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