Abstract
Reactions between R 3PAuCl, NaOEt, and HCCR′ under mild conditions produce R 3PAuCCR′ in excellent yield. When R′ = H, a second step leading to the formation of R 3PAuCCAuPR 3 can take place. Exchange reactions of ethynyl for chloride between the ethynylgold complexes and HgCl 2, cis-[PtCl 2L 2 cis-[PtCl 2(CO)L], and R 2″PAuCl have been monitored, revealing R 3PAuCCR′ to be useful alkynylating agents. In the reaction with cis-[PtCl 2(CO)L], the first substitution step is non-specific.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
