Abstract

The title compound, [(NH3)2(CH2)2][Fe(SO4)2(H2O)4], contains centrosymmetric [Fe(H2O)4(SO4)2]2− anions, with a coordination octahedron around iron(II) built up from four water mol­ecules and two sulfate groups. The anions are linked by hydrogen bonds of medium strength, forming a three-dimensional framework. The linkage is reinforced by N—H⋯O bridges from the centrosymmetric [NH3(CH2)2NH3]2+ cations, located in the centre of the interstices.

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