Abstract
Three versions of zirconium-based metal organic frameworks, NH2–UiO-66, GMA-UiO-66, and EDA-UiO-66, were synthesized and employed as adsorbent for CO2/CH4 separation. GMA-UiO-66 was synthesized via a ring opening reaction between the amine species in the framework and epoxy groups in glycidyl methacrylate (GMA), while the green aza-Michael addition reaction was used for the first time to functionalize GMA-UiO-66 with ethylenediamine (EDA). The products were characterized by BET, XRD, TGA, FESEM, ICP-OES, 1H NMR, mass spectroscopy, and FTIR-ATR methods to monitor their textural properties before and after functionalization. The results indicated that GMA was successfully grafted to the NH2–UiO-66 framework, and most of the alkene groups were grafted with EDA, which indicated that the Michael addition reaction was very effective. The experimental gas adsorption results indicated that the EDA-grafted UiO-66 possessed the highest CO2 adsorption capacity as well as CO2/CH4 selectivity due to the introduction o...
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