Abstract
AbstractEthylene copolymerization with 1,3‐cyclohexadiene (CHD) was investigated by using methylaluminoxane (MAO) activated single‐site catalysts including bridged and non‐bridged titanium half‐sandwich and bimetallic cobalt(I) complexes. MAO activated CpTiCl2[NP(tBu)3] (Cp = cyclopentadienyl, tBu = tert‐butyl) gave high molecular weight CHD copolymers without encountering catalyst activity losses. According to the NMR microstructure investigation the resulting copolymers are highly regioregular.
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