Abstract
In the crystals of the title compounds, C 8 H 16 N 2 S 4 (I), and C 10 H 20 N 2 S 4 , (II), the molecules lie about inversion centres. In both structures, the C=S bonds in the two dithiocarbamate units are oriented trans to each other. In (I), the ethylene bridge and the bridged S atoms adopt a trans planar conformation and form a dihedral angle of 84.4 (2)° with the dimethyldithiocarbamate plane. The molecule of (II) is nearly planar; in the crystal the molecules are arranged in sheets which are stacked, 3.874 (2) A apart, parallel to (206) planes.
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