Abstract

The title compound, C31H26N4O2S, crystallizes in a triclinic centrosymmetric lattice with two molecules in the unit cell. The five-membered thiazole and pyrrolidine rings adopt twisted and envelope conformations, respectively. The methoxyphenyl and indenoquinoxaline planes are oriented with a dihedral angle of 88.1 (1)° to each other. The crystal structure features C—H...N, C—H...O and C—H...S intermolecular interactions forming two R 2 2(16) ring motifs and a C(11) and two C 2 2(14) chain motifs. The –CH3 group of the ethyl side chain is disordered over two positions with site occupancies of 0.55 and 0.45.

Highlights

  • The title compound, C31H26N4O2S, crystallizes in a triclinic centrosymmetric lattice with two molecules in the unit cell

  • The methoxyphenyl and indenoquinoxaline planes are oriented with a dihedral angle of 88.1 (1) to each other

  • The –CH3 group of the ethyl side chain is disordered over two positions with site occupancies of 0.55 and 0.45

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Summary

Structure description

The fusion of more heterocyclic rings, such as thiazoles, pyrrolidines and quinoxalines, in a single compound is being investigated by many researchers around the world due to the versatile applications of such compounds in the biological and pharmaceutical industries (He et al, 2003; Swarnkar et al, 2007; Verma & Saraf, 2008; Muralikrishnan et al, 2013). When such a fused heterocyclic compound has attached donor and acceptor groups, it leads to intermolecular interactions which are normally weak hydrogen bonds.

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Synthesis and crystallization
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