Abstract

The title compound, C13H13BrO4S, was prepared by the oxidation of ethyl 2-(5-bromo-3-methyl­sulfanyl-1-benzofuran-2-yl)acetate using 3-chloro­perbenzoic acid. The O atom and methyl group of the methylsulfinyl substituent lie on opposite sides of the plane of the benzofuran moiety. The crystal structure is stabilized by inter­molecular π–π inter­actions [centroid-to-centroid separation = 3.592 (2) Å], as well as by C—H⋯O hydrogen bonds.

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