Abstract
The relative rates of racemization of chiral organometallic reagents can be obtained by reaction of the racemic reagent with a chiral aldehyde–in one experiment, racemic, in the other, enantiomerically pure [Eq. (a)]. The greater the configurational stability of the reagent, the larger the difference in the product ratios for the racemic and the enantiomerically pure aldehyde.
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Schedule a callMore From: Angewandte Chemie International Edition in English
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