Abstract
Contributions and corrections for the estimation of standard Gibbs energies are given. The group contribution method, applicable to both cyclic and acyclic compounds, permits the approximate estimation of the standard Gibbs energy of a biotransformation, given the stoichiometry and structures of the metabolites involved. Estimated standard Gibbs energies of formation for a number of acyclic biochemical compounds are provided.
Highlights
From the Systems Research Center and Departmentof Chemical Engineering, A
It was previously mentioned that the concentrations of water and the concentrations of
The first contribution in TablIe refers to theorigin, which is used as the initial quantity for the Gibbs energy of any biochemical compound
Summary
From the Systems Research Center and Departmentof Chemical Engineering, A. Contributions and corrections for the estimation of Gibbs energy change of the transformation canbe expressed standard Gibbs energies are given. Estimated standard Gibbs energies of formation for a number of acyclic biochemical compounds are provided. The standardGibbs energies of formation of a number of biochemical compounds allow thedetermination of the standard Gibbs energychange (and thequilibrium constant) of any transformation that involves only these biochemical compounds. In the rest of this article, the term "Gibbs energy" will are common toolsfor the thermodynamic analysiosf biotrans- be used for both the standard Gibbs energy of formation of a formations Throughout this article, these quantiwtieilsl refer compound and the standard Gibbsenergy change of a transt o concentrations rather than activities
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