Estimation of physicochemical characteristics and associated metal contamination risk in the Narmada River, India

Abstract

River Narmada is the fifth largest holy river of Madhya Pradesh (M.P) flowing in the central part of India. The river receives large quantity of untreated/partially treated wastewater enriched with heavy metals and supplementary toxic organic pollutants. This study aims to assess the water quality status in river Narmada using indices like comprehensive pollution index (CPI), heavy metal pollution index (HPI), risk assessment index (RAI) and cancer risk index (CRI), for human use. The presence of faecal coliform and high chemical oxygen demand > 20 mg/L indicates that the water is unsuitable for drinking purposes. The average CPI and HPI evaluated to be 1.98, and 1.35, respectively signifies the moderately polluted river water. Considerably, the RAI > 1 and CRI > 1 is obtained at all sampling locations that alarms the possible cancer risk to human if untreated river water is used. Principal component analysis of data confirmed pollution in the river from both natural and anthropogenic sources. The strongest Pearson correlation coefficient between Cu-Pb (0.998) and Zn-Cu (0.986) indicates the input of wastewater in the river probably from electroplating industries. The river water is unsuitable for human intake. It is required to control direct flow of wastewater in river to restore ecological health.