Estimation of Densities of Aqueous Actinide Solutions Ranging from Pure Water to Hydrated Crystals

Abstract

The density of aqueous solutions containing actinide nitrates is an important parameter for process design, equipment design, and remote operation/control. It is also significantly important for the estimation of atom densities during criticality calculations and related experiments involving actinide solutions. Using a massive database of 1353 points consisting of in-house-generated data as well as data published in the literature, a robust estimation of the coefficients of a re-parameterized and dimensionally consistent form of density equation was performed in the following range of parameters: U(VI) concentration 0 to 1330 g/L, Pu(IV) concentration 0 to 1201 g/L, HNO3 concentration 0 to 15.8 M, and temperature range of 283.15 to 373.15 K. This paper lists the details of the new database, the newly estimated coefficients, and the performance evaluation of the proposed re-parameterized dimensionally consistent equations.