Abstract

This study presents the test results of 8 concrete series in 5% sulfuric acid solution for 28, 56 and 180 days. Each series was made using two mixtures based on CEM II/A-S 32.5 and CEM III/A 32.5 cements. Modification of the properties of concrete was obtained by the introduction of superplasticizer, silica fume, complex of structure modifier and hydrophobic admixture. The water-binder ratio varied from 0.27 to 0.63, the compressive strength was 26 to 83 MPa, and water absorption from 3.4 to 8.4 %. Samples of test cubes (10x10x10 cm) and test beam (16x4x4 cm) were prepared to immersion in the acid solution. The assessment of corrosion resistance was carried out on the weight loss and strength of concrete in relation to the initial value of 28 days. The obtained results showed that the surface layer of concrete in all samples was destroyed after 28 days of exposure. The deterioration of the corrosion resistance of modified concrete in relation to ordinary concrete without additives was observed regardless of the type of cement. An exception was a series of concrete, which had a water-binder ratio of 0.27–0.28 and a compressive strength of 77–83 MPa.

Highlights

  • In Ukraine, sewer tunnels, most of which were constructed 40–50 years ago from ordinary concrete (C16/20, C20/25), are in the bad or emergency condition

  • This study presents the test results of 8 concrete series in 5% sulfuric acid solution for 28, 56 and 180 days

  • The greatest effect of reducing water absorption was achieved by the introduction of superplasticizer, which allowed reducing the amount of water and water-binder ratio (W/B)

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Summary

Introduction

In Ukraine, sewer tunnels, most of which were constructed 40–50 years ago from ordinary concrete (C16/20, C20/25), are in the bad or emergency condition now. In Ukraine, sewer tunnels, most of which were constructed 40–50 years ago from ordinary concrete (C16/20, C20/25), are in the bad or emergency condition This has been caused by the intensive impact of destructive factors, among which the influence of sulfuric acid of biogenic origin is most significant [1, 2]. Restoration of their operational characteristics to extend the trouble-free life of the service is an expense and difficult problem. Improving the concrete mixture design is still a viable method because it changes the rate of the corrosion reaction process [3]

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