Estimation of boron isotope ratios using high resolution continuum source atomic absorption spectrometry

Abstract

In the production of 10B enriched steels, the production–recycling process needs to be closely monitored for inadvertent mix-up of materials with different B isotope levels. A quick and simple method for the estimation of boron isotope ratios in high alloyed steels using high resolution continuum source flame AAS (HR-CS-FAAS) was developed. On the 208.9 nm B line the wavelength of the peak absorption of 10B and 11B differs by 2.5 pm. The wavelength of the peak absorption of boron was determined by fitting a Gauss function through spectra simultaneously recorded by HR-CS-FAAS. It was shown that a linear correlation between the wavelength of the peak absorption and the isotope ratio exists and that this correlation is independent of the total boron concentration. Internal spectroscopic standards were used to compensate for monochromator drift and monochromator resolution changes. Accuracy and precision of the analyzed samples were thereby increased by a factor of up to 1.3. Three steel reference materials and one boric acid CRM, each certified for the boron isotope ratio were used to validate the procedure.