Abstract

The proposed composition for anti-icing coating of metal structures. The composition contains as the filler used aerosil brand R 972 with a density of 2360 kg / m3, particle size of 16 nm and a specific surface 12000 m2 / kg. Silicone resin SILRES® MSE 100 with a 10% concentration was used as a binder. The degree of hydrophobicity was estimated by the value of the wetting angle. In order to characterize the anti-icing properties of the coatings, we used the static and dynamic (advancing and retreating) wetting angle, as well as wetting hysteresis, for which we measured the angles of leakage, and the angles of drift from. Studies of the dynamics of freezing drops on the surface were performed using a TESTO 875-1 thermal imager. It is shown, that the hysteresis of wetting of the superhydrophobic surface based on the developed composition is 3.7 degrees. The critical angle of rolling drops of water from an inclined surface is determined. In the study of the kinetics of freezing of a drop of water on a metal surface, an uneven distribution of temperature on the surface of a drop of water is observed. The process of freezing drops is multistage. In the initial period, there is a transfer of heat from the surface to a drop of water. This stage is followed by the process of freezing the drop, which is manifested in the movement of the freezing front from the substrate upwards.

Highlights

  • - the duration of the contact of the superhydrophobic surface with the falling drop is so small that the drop does not have time to freeze [2,3];

  • - high mobility of liquid droplets on the surface of the coating, which is determined by the small hysteresis of the wetting angle - no more than 10–15 degrees [4,5];

  • The results of the studies showed that after wetting for 72 hours a coating based on SILRES® MSE100 silicone resin of 5% and 10% concentration retained a superhydrophobic effect - the wetting angle on the mortar substrate was more than 150 degrees

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Summary

Introduction

Various anti-icing coatings are used to protect the roofs of buildings against icing.The effectiveness of anti-icing coatings due to their unique properties:. - high mobility of liquid droplets on the surface of the coating, which is determined by the small hysteresis of the wetting angle - no more than 10–15 degrees [4,5];. - low adhesion of ice to the surface, due to a small fraction of the wetted surface (~ 100 kPa), and anti-corrosion properties [6,7]. Our studies allowed us to recommend the composition for anti-icing coating containing silicone resin SILRES® MSE 100 and aerosil brand R 972 [12]. The results of the studies showed that after wetting for 72 hours a coating based on SILRES® MSE100 silicone resin of 5% and 10% concentration retained a superhydrophobic effect - the wetting angle on the mortar substrate was more than 150 degrees. Methods for determining adhesion "after wetting amounted to 1 point

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