Estimating soil organic carbon content at variable moisture contents using a low-cost spectrometer

Abstract

Research-grade spectrometers such as ASD are widely used in the lab to estimate soil properties, but they are bulky, heavy, and not easily deployable to measure field soils. The newer FT-NIR spectrometers are compact, lightweight, and robust, suitable for developing portable sensors for emerging applications such as field-based soil carbon stock assessment. In this study, we investigated the usefulness of an FT-NIR spectrometer (NanoQuest) for estimating SOC content while correcting for the effect of soil moisture using External Parameter Orthogonalization (EPO), and its performance was compared to that of ASD. To develop EPO transformation, five levels of soil moisture were used at 0, 0.07, 0.13, 0.18, 0.24, and 0.30 g g−1. We tested two modeling approaches: Partial Least Squares Regression (PLSR) and Support Vector Regression (SVR). The results showed that EPO was more effective in correcting for the moisture effect as samples became drier. ASD gave a better performance in estimating SOC with SVR (R2: 0.17 to 0.84, RMSE: 6.1 to 3.9 g C kg−1, bias: −0.3 to 0.1 g C kg−1) after EPO transformation. NanoQuest gave slightly lower, but still satisfactory performance in SOC estimation (R2: 0.17 to 0.70, RMSE: 9.2 to 5 g C kg−1, bias: −0.3 to 0.1 g C kg−1). EPO substantially reduced the bias of the SOC models for both ASD and NanoQuest. This study demonstrates the usefulness of low-cost FT-NIR spectrometers for SOC measurement at varying moisture contents and their great potential for field-deployable soil sensor development.