Establishing the nature of kinetic effects of the high-temperature oxidation (combustion) process of some liquid organic matters by acoustic radiation

Abstract

In this article, the results of the study on the physicochemical characteristics of some liquid organic matters on the kinetics of their high-temperature oxidation (combustion) were presented for the first time. These results were obtained by the method of acoustic emission spectrum from heat source. The research results of the amplitude-time characteristics (until cessation of combustion completely) and the frequency response functions (in a given frequency range) of oxidation (combustion) process of liquid organic matters showed that there are following unambiguous dependences: 1) the dependences of the number of the amplitude maximum of the frequency and time spectrum in a given frequency range, as well as of the fractal dimension of the received acoustic signal on the number of carbon atoms in the carbon frame of organic matters and their molar mass; and 2) the dependences of the time of beginning of the combustion (ignition) of primary cloud of organic matters vapors and the final combustion time of the primary cloud of organic matters vapors on the number of carbon atoms in the carbon frame of the organic matters and their partial vapor pressures. The practical aspect of using the results obtained is dictated by the need to develop standard samples of amplitude-time and amplitude-frequency characteristics, depending on the physicochemical and combustible properties of the organic matters. This is necessary for the data bank of the acoustic emission monitoring system to establish a fire hazardous state and make anti-crisis decisions at critical infrastructure facilities.