Abstract
Spin-adducts of boron-centered radicals, derivatives ofm-carboran-12, with fullerenes C60 and C70 have been studied by ESR spectroscopy. Constants of hyperfine splitting (HFS) of an unpaired electron with10B and11B nuclei have been determined from the ESR spectra of C60-B10H9C2H2 radicals. Three isomeric spin-adducts were detected with different HFS constants with11B, andg-factors were detected in the reaction of B10H9C2H2 with C70.
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