Abstract
ESR line shape measurements of dilute Cu(NO 3) 2 solution in liquid ammonia in the temperature range 195–300 °K are reported. The line shape analysis of the four resolved copper hyperfine components indicates that the relaxation mechanisms of the electron spin mainly arise from anisotropic g and hyperfine interaction by tumbling motion and from spin-rotational interaction. A very small linewidth contribution due to unresolved 14N ligand hyperfine structure is discussed in terms of motional narrowing.
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