Abstract
The products of photolysis of the long-lived radical [(CF3)2CF]2C·C2F5 at 77 K were studied by ESR. The mechanism of photodecomposition to form ·CF3 radicals was proposed. The ESR spectra of the trifluoromethyl radicals stabilized at 77 K in a glassy hexafluoropropylene trimer matrix were simulated, and the parameters A∥ = 25.15 mT, A⊥ = 9.1 mT, and g∥ = l.9996, g⊥ = 2.0056 were determined.
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