Abstract
Phthalocyanine complexes of paramagnetic metal ions show ESR spectra characteristic of the metals; phthalocyanine complexes of diamagnetic metal ions show strong single ESR lines characteristic of free radicals. The source of this latter resonance is not understood. Intimate molecular mixtures of ``paramagnetic'' copper and ``dimagnetic'' zinc phthalocyanines exhibit exchange between the copper unpaired electron and the ``free radical'' electron in the zinc phthalocyanine. Nickel and zinc phthalocyanine also exhibit a single sharp resonance in dilute solutions of concentrated sulfuric acid.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
