Abstract
ESR results of low concentrated systems Pb1-x{Gd,Sc}xF2+x at temperatures up to 775 K are reported. At room temperature, ESR-spectra of single crystals and polycrystalline samples show three sets of lines which are correlated to different Gd-sites. The observed shift of the line positions with increasing temperature is caused by the decreasing crystal field interaction. There is no temperature dependence of the differential linewidth until about 600 K. At higher temperatures we observed a drastic increase of the linewidth, correlated to the faster relaxation upon transition to the superionic state.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Berichte der Bunsengesellschaft für physikalische Chemie
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
