Abstract

The intrinsic point defects of GaP nano-solids have been investigated by means of electron spin resonance (ESR). An ESR spectrum attributed to the Ga self-interstitial in GaP nano-solids was observed with value g=2.0028 or 2.0030. The collapse of hyperfine splitting and narrowing of peak-to-peak linewidth (Δ H pp) of the ESR spectrum result from the possible rapid electron spin exchange effect. The concentration of dangling bonds for GaP nano-solids decreases when decreasing compaction pressure and with higher heat-treatment temperature. Both detection and control of the intrinsic point defects of nano-sized GaP materials are beneficial for further exploration of its fundamental properties and applications.

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