Abstract
( E)-Crotyltrimethylsilane and ( E)-cinnamyltrimethylsilane were allowed to react with aldehydes (RCHO: R = t-Bu, i-Pr, Et, Me) in the presence of titanium chloride to give erythro homoallyl alcohols with over 93% selectivity. Lower erythroselectivity was observed in the reaction of (Z)-allylsilanes.
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