Abstract

Reaction of β-ethylthio-β-lithioacrylate with α-chloroaldehydes furnished predominantly the erythro products I, which were isolated as γ-lactones; At room temperature intermediates I are transformed into the (±)-erythro-γ,δ-dihydroxycarboxylic acid γ-lactones. Raney nickel treatment provided interesting natural γ-lactone derivatives

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