Abstract
Abstract The experimental evaluation of the rate constant for weak acid ionization in aqueous solution by electric field jump methods is subject to very large errors when pKa for the acid becomes about 6 or greater. For stronger acids the error becomes equal to or less than the experimental precision. It is therefore recommended that for acids with pKa 6 or greater the rate constant for ionization be evaluated from the rate constant for ion combination and the equilibrium constant.
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