Abstract
Gasoline engine oil (SAE 5W-20) was subjected to thermal oxidization (TO) for four periods of time (0 h, 48 h, 96 h and 144 h) and exposed to THz-time domain spectroscopy (TDS) measurement. Error contributions from various error sources, such as repeatability errors, assembly errors of the probe volume and errors caused by the TDS system were evaluated with respect to discernibility and significance of measurement results. The most significant error source was due to modifications of the TDS setup, causing errors in the range of 0.13% of the refractive index for samples with a refractive index around 1.467 and a probe volume length between 5 and 15 mm at 1 THz. The absorption coefficient error was in the range of 8.49% for an absorption around 0.6 cm−1. While the average of measurements taken with different setup configurations did not yield significant differences for different TO times, a single, fixed setup would be able to discern all investigated oil species across the entire frequency range of 0.5–2.5 THz. The absorption coefficient measurement showed greater discernibility than the measurement of the refractive index.
Highlights
Terahertz (100 GHz–10 THz) sensor systems feature unique advantages in comparison to other spectral ranges, such as inspection of optically opaque substances [1]
Three different error sources of the time domain spectroscopy (TDS) measurement were investigated: (i) statistical or repeatability errors caused by the measurement technique; (ii) systematic errors caused by the sample preparation, that is, due to errors in sample volume length by disassembly and reassembly
All errors presented in this manuscript correspond to the 95% confidence interval of CI = 1.96σ, where σ is the standard deviation
Summary
Terahertz (100 GHz–10 THz) sensor systems feature unique advantages in comparison to other spectral ranges, such as inspection of optically opaque substances [1]. Substances with narrow spectral features are being investigated and broadband studies of the refractive index or the absorption coefficient vs frequency [2]. A manifold of spectroscopic results have been obtained using broadband Terahertz time domain (TDS) spectroscopy, such as refractive indices and absorption coefficients of semiconductors [3] and various kinds of plastics [4]. We selected thermally oxidized engine oil with oxidation times from 0 h to 144 h This is a interesting study object for both error analysis and scientific reasons. Operators replace engine oil while it still has useful life; resulting in unnecessarily wasted engine oil. Both scenarios result in potential economic losses. In the absence of other contaminants, oxidation of oil during engine operation limits the useful life of engine oil
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